Treatment of antimony mine wastewater by mechanism charcoal and calcium carbonate

Through the mechanism of charcoal and calcium carbonate on the treatment of antimony ore wastewater, find the most economical and effective method for the treatment of antimony mine wastewater. The mine water in a typical antimony ore polluted area was sampled, and its content of antimony, arsenic and mercury were determined by hydride atomic fluorescence spectrometry and compared with national emission standards. The treatment of strontium, arsenic and mercury was carried out by using the methods of charcoal and calcium carbonate respectively. The results show that the adsorption and filtration of the mechanism charcoal can reduce the strontium content in the strontium mine wastewater from 5 557.44-5 714.01 μg / L to 40.11 μg / L. The adsorption of powdered calcium carbonate can minimize the strontium content of wastewater. 83.97μg / L (P <0.05), and calcium carbonate has a good regulation effect on the mine wastewater with high acidity (pH = 3) (pH is about 7.8). It has been shown to be toxic, carcinogenic to humans and other organisms, and can cause diseases in the liver, skin, respiratory and cardiovascular systems, and sputum poisoning has a long incubation period.

Antimony pollution mainly from antimony and antimony-containing metal smelting or coal mining, industrial production has a certain amount of antimony into the atmosphere, water, soil, causing an increase in the antimony content in some areas, resulting in environmental pollution. Acidic wastewater generated from antimony mining is also an important cause of environmental (especially watershed environment) pollution. When it is dissolved in water, it is easily absorbed by plants and migrates and accumulates in plants. China is the country with the most abundant reserves in the world. It is mainly concentrated in southern provinces such as Hunan, Guizhou and Guangxi. The cold water tin mine in Hunan and the Shandong Shandong peak in Guizhou are famous in China.

At present, there are many treatment methods for antimony ore wastewater, mainly adsorption methods (such as adsorption with activated carbon (AC)), electrochemical methods (such as micro-electrolysis), and chemical precipitation methods (such as adjusting pH or adding flocculant). . For example, Zhang Weining and others use the partial deposition method to remove the ruthenium in the metal alloy solution, first adjust the pH = 5-6, filter the solution through the membrane, wash and dry, then adjust the pH = 9-10, membrane filtration, washing, drying. By this method, the radon concentration can be reduced from 300 × 10-6 to 25 × 10-6. Zhang et --- micro electrolysis process and the precipitation mine drainage, acid waste water so that the reactor through the column filled with coke and scrap iron and then adding an alkali and water, after treatment, the water content can antimony 28mg / L Reduced to 0.14 mg / L.

After the on-site sampling of the Dongfengyu mine water in Dushan County, the pollution status of heavy metals such as strontium in the mine water of Dongfeng Mine was analyzed. The treatment effect of the charcoal and calcium carbonate on the wastewater of the mine was studied. Atomic fluorescence spectrometer was used to determine the content of heavy metal elements in barium, arsenic and mercury before and after treatment, which provided a technical reference for the development of antimony ore pollution control technology. The sample was collected in November 2011. The mine effluent from the Dongfengyu mining area in Dushan County, Guizhou Province was used as the sample collection object, and the effluent from the mine effluent and the lime neutralization treatment tank was collected. It is packed in a polyethylene plastic bucket. Samples are transported back to the laboratory immediately after collection, protected from light and shaken while in use. AF640-Hydride Generation Atomic Fluorescence Spectrometer (Ruimai Analytical Instruments); one in ten electronic analytical balance; cesium, arsenic, mercury hollow cathode lamp; ultrapure water system; electronic stirrer; portable pH meter. Calcium carbonate adjusts the pH value of the mine water: Weigh 2.0 g of calcium carbonate in a 250 mL beaker, add 150 mL of mine wastewater, place it in a magnetic stirrer and mechanically stir it, and measure its pH every 3 minutes. Charcoal adjustment of the pH value of the mine water: Take a 300 mm × 10 mm glass column, fill the charcoal to a height of about 100 mm, slowly inject the waste water from the mine with a 50 mL beaker, and use a 500 mL beaker to filter the filter. The solution was measured and its pH was measured every 2 minutes.

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